Photolysis of 3-(2,2,2-triphenylethoxy)-3-chlorodiazirine gives 2,2,2-triphenylethoxychlorocarbene which fragments with 1,2-phenyl migrationand loss of CO and Cl
- to yield the 1,1,2-triphenylethyl cation and thence 1,1,2-triphenylethene by proton loss. However, ps and fs laser flashphotolysis provides evidence that up to 25% of the alkene product stems from carbocation that arises directly from excited diazirine ratherthan from the carbene.