Bottom-Up Crystal Engineering toward Nanoporosity Exemplified by a Zinc Carboxylate Coordination Polymer Adopting a Tenorite Analogue Network Topology

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• 作者：Kuang-Lieh Lu ; Yen-Fu Chen ; Yen-Hsiang Liu ; Yi-Wei Cheng ; Rong-Tang Liao ; and Yuh-Sheng Wen
• 刊名：Crystal Growth & Design
• 出版年：2005
• 出版时间：March 2005
• 年：2005
• 卷：5
• 期：2
• 页码：403 - 405
• 全文大小：267K
• 年卷期：v.5,no.2(March 2005)
• ISSN：1528-7505

文摘

A bottom-up approach to the design of a coordination polymer, [(K₂)Zn(btec)·8H₂O]_n, adopting a nanoscopictenorite (CuO) analogue network topology with an increase in pore size from 0.343 to 1.134 nm is described (Kbtec =potassium 1,2,4,5-benzenetetracarboxylate).