文摘
Acceptorless, reversible dehydrogenation and hydrogenation reactions involving N-heterocycles are reported with a well-defined cobalt complex supported by an aminobis(phosphine) [PN(H)P] pincer ligand. Several N-heterocycle substrates have been evaluated under dehydrogenation and hydrogenation conditions. The cobalt-catalyzed amine dehydrogenation step, a key step in the dehydrogenation process, has been independently verified. Control studies with related cycloalkanes suggest that a direct acceptorless alkane dehydrogenation pathway is unlikely. The metal鈥搇igand cooperativity is probed with the related [PN(Me)P] derivative of the cobalt catalyst. These results suggest a bifunctional dehydrogenation pathway and a nonbifunctional hydrogenation mechanism.