FeCl3·6H2O Catalyzed Disproportionation of Allylic Alcohols and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol
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- 作者：Jialiang Wang ; Wen Huang ; Zhengxing Zhang ; Xu Xiang ; Ruiting Liu ; Xigeng Zhou
- 刊名：Journal of Organic Chemistry
- 出版年：2009
- 出版时间：May 1, 2009
- 年：2009
- 卷：74
- 期：9
- 页码：3299-3304
- 全文大小：199K
- 年卷期：v.74,no.9(May 1, 2009)
- ISSN：1520-6904
文摘
Iron chloride has been found to be an efficient catalyst for the disproportionation of allylic alcohols, which provides a convenient method for selective transformation of allylic alcohols to alkenes and α,β-unsaturated ketones. Furthermore, this catalytic system is also effective for highly selective allylic reduction of allylic alcohols, allylic ethers, and allylic acetates with benzyl alcohol under neutral and convenient reaction conditions.