|(C4NH12)4|[M4Al12P16O64] (M = Co, Zn): New Heteroatom-Containing Aluminophosphate Molecular Sieves with Two Intersecting 8

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• 作者：Zhuo Liu ; Xiaowei Song ; Jiyang Li ; Yi Li ; Jihong Yu ; Ruren Xu
• 刊名：Inorganic Chemistry
• 出版年：2012
• 出版时间：February 6, 2012
• 年：2012
• 卷：51
• 期：3
• 页码：1969-1974
• 全文大小：444K
• 年卷期：v.51,no.3(February 6, 2012)
• ISSN：1520-510X

文摘

Two novel heteroatom-containing aluminophosphate molecular sieves, |(C₄NH₁₂)₄|[M₄Al₁₂P₁₆O₆₄] (denoted MAPO-CJ69, M = Co and Zn), have been solvothermally synthesized using diethylamine as the structure-directing agent. The framework of MAPO-CJ69 exhibits a new zeolite topology which is constructed by strict alternation of metal-centered (Al/M)O₄ tetrahedra and PO₄ tetrahedra to form a three-dimensional anionic [M₄Al₁₂(PO₄)₁₆]^{4鈥?/sup> framework. The structure contains two intersecting 8-ring channels along the [010] and [001] directions, and the protonated diethylamine cations reside in the 8-ring channels to achieve charge neutrality. The structure of MAPO-CJ69 is composed of the 4-4- secondary building unit (SBU), which has been found in some known zeolites, such as AFR, SFO, ZON, OWE, etc. The structural relationships between these zeolites have been discussed.}