Coordination Programming of Two-Dimensional Metal Complex Frameworks

详细信息    查看全文

• 作者：Hiroaki Maeda ; Ryota Sakamoto ; Hiroshi Nishihara
• 刊名：Langmuir
• 出版年：2016
• 出版时间：March 22, 2016
• 年：2016
• 卷：32
• 期：11
• 页码：2527-2538
• 全文大小：871K
• 年卷期：
  Hiroaki Maeda was born in Toyama prefecture, Japan in 1987. He received his B.Sc. in 2010, M.Sc. in 2012, and Ph.D. in 2015 from The University of Tokyo. His resent research interest lies in the stepwise preparation of metal complex wires on electrodes and their electrochemical evaluation and syntheses of coordination nanosheets using interfacial reactions.
  Ryota Sakamoto was born in Yamagata Village, Nagano, Japan in 1980. He graduated from The University of Tokyo in 2002 and received his Ph.D. from the same university in 2007 under the supervision of Prof. Hiroshi Nishihara. Then he was appointed as an assistant professor at Tokyo University of Science, working with Prof. Takeshi Yamamura. In 2010, he moved to The University of Tokyo, joining Prof. Nishihara’s group again. His current research interest lies in the construction of molecule-based nanostructures and photonic and electronic devices using these nanostructures.
  Hiroshi Nishihara received his B.Sc. in 1977, M.Sc. in 1979, and D.Sc. in 1982 from The University of Tokyo. He was appointed a research associate in the Department of Chemistry at Keio University in 1982, and he was promoted to lecturer in 1990 and associate professor in 1992. Since 1996, he has been a professor in the Department of Chemistry, School of Science, The University of Tokyo. He also worked as a visiting research associate in the Department of Chemistry at The University of North Carolina at Chapel Hill (1987–1989) and as a researcher at PRESTO, JST (1992–1996). He received a Docteur Honoris Causa from University of Bordeaux in 2011, a Commendation for Science and Technology by MEXT in 2014, a Japan Society of Coordination Chemistry Award in 2015, and a Chemical Society of Japan Award in 2016.
• ISSN：1520-5827

文摘

Since the discovery of graphene, two-dimensional materials with atomic thickness have attracted much attention because of their characteristic physical and chemical properties. Recently, coordination nanosheets (CONASHs) came into the world as new series of two-dimensional frameworks, which can show various functions based on metal complexes formed by numerous combinations of metal ions and ligands. This Feature Article provides an overview of recent progress in synthesizing CONASHs and in elucidating their intriguing electrical, sensing, and catalytic properties. We also review recent theoretical studies on the prediction of the unique electronic structures, magnetism, and catalytic ability of materials based on CONASHs. Future prospects for applying CONASHs to novel applications are also discussed.