Production of Molybdenum Trioxide Nanosheets by Liquid Exfoliation and Their Application in High-Performance Supercapacitors

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• 作者：Damien Hanlon ; Claudia Backes ; Thomas M. Higgins ; Marguerite Hughes ; Arlene O鈥橬eill ; Paul King ; Niall McEvoy ; Georg S. Duesberg ; Beatriz Mendoza Sanchez ; Henrik Pettersson ; Valeria Nicolosi ; Jonathan N. Coleman
• 刊名：Chemistry of Materials
• 出版年：2014
• 出版时间：February 25, 2014
• 年：2014
• 卷：26
• 期：4
• 页码：1751-1763
• 全文大小：611K
• 年卷期：v.26,no.4(February 25, 2014)
• ISSN：1520-5002

文摘

Here, we demonstrate a simple method to exfoliate layered molybdenum trioxide (MoO₃) crystallites to give multilayer MoO₃ nanosheets dispersed in solvents. Exfoliation is achieved by sonicating MoO₃ powder in the presence of suitable solvents followed by centrifugation to remove undispersed material. This procedure works well in a range of solvents with Hildebrand solubility parameters close to 21 MPa^1/2 and is consistent with the predictions of classical solubility theory. We have fully optimized this process and demonstrated methods to separate the resultant nanosheets by size. Raman spectroscopy suggests the exfoliation process does not damage the MoO₃. This is supported by measurements showing that the reaggregated nanosheets display very similar photoluminescence to bulk MoO₃. However, the dispersed nanosheets had distinctly different photoluminescence, indicating a decoupling of the monolayers on exfoliation. We have used liquid-exfoliated MoO₃ to prepare supercapacitor electrodes that have relatively low capacitance (2 F/g at 10 mV/s) because of the low electrical conductivity of the MoO₃. However, addition of carbon nanotubes beyond the percolation threshold yielded a 100-fold increase in capacitance. Some MoO₃/nanotube composites displayed a capacitance as high as 540 F/g at 0.1 mV/s. This is the first example of solvent exfoliation of a layered metal oxide. We believe this work opens the way to liquid exfoliation of a wide range of layered compounds, leading to an array of new solution-processed 2D materials.