A Tetracoordinated Rhodium Aminyl Radical Complex
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- 作者：Pascal Maire ; Martin Kö ; nigsmann ; Anandaram Sreekanth ; Jeffrey Harmer ; Arthur Schweiger ; and Hansjö ; rg Grü ; tzmacher
- 刊名：Journal of the American Chemical Society
- 出版年：2006
- 出版时间：May 24, 2006
- 年：2006
- 卷：128
- 期：20
- 页码：6578 - 6580
- 全文大小：173K
- 年卷期：v.128,no.20(May 24, 2006)
- ISSN：1520-5126
文摘
A [16 + 1] valence electron configured rhodium aminyl radical complex could be synthesized and characterized in detail by pulse EPR spectroscopy and DFT calculations. The unpaired electron is delocalized over the metal center and two adjacent nitrogens. H-abstraction reactions from thiols and triethylsilane show that the spin density is predominantly localized on both nitrogens.