Trimerization of Ethylene to 1-Hexene with Titanium Complexes Bearing Phenoxy−Imine Ligands with Pendant Donors Combined with MAO
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- 作者：Yasuhiko Suzuki ; Shinsuke Kinoshita ; Atsushi Shibahara ; Seiichi Ishii ; Kazumori Kawamura ; Yoshihisa Inoue ; Terunori Fujita
- 刊名：Organometallics
- 出版年：2010
- 出版时间：June 14, 2010
- 年：2010
- 卷：29
- 期：11
- 页码：2394-2396
- 全文大小：671K
- 年卷期：v.29,no.11(June 14, 2010)
- ISSN：1520-6041
文摘
New Ti complexes bearing phenoxy−imine ligands with pendant aryl−OMe donors have been developed for ethylene trimerization to produce 1-hexene. These Ti complexes combined with methylaluminoxane selectively trimerize ethylene to form 1-hexene with exceptionally high activity (e.g., 6.59 tons of 1-hexene/((g of Ti) h)) .