文摘
The crystal phase of nanostructured metal oxide can be effectively controlled by the hybridization of gallium oxide with reduced graphene oxide (rGO) at variable concentrations. The change of the ratio of Gab>2b>Ob>3b>/rGO is quite effective in tailoring the crystal structure and morphology of nanostructured gallium oxide hybridized with rGO. This is the first example of the phase control of metal oxide through a change of the content of rGO hybridized. The calculations based on density functional theory (DFT) clearly demonstrate that the different surface formation energy and Ga local symmetry of Gab>2b>Ob>3b> phases are responsible for the phase transition induced by the change of rGO content. The resulting Gab>2b>Ob>3b>鈥搑GO nanocomposites show promising electrode performance for lithium ion batteries. The intermediate Li鈥揋a alloy phases formed during the electrochemical cycling are identified with the DFT calculations. Among the present Gab>2b>Ob>3b>鈥搑GO nanocomposites, the material with mixed 伪-Gab>2b>Ob>3b>/尾-Gab>2b>Ob>3b>/纬-Gab>2b>Ob>3b> phase can deliver the largest discharge capacity with the best cyclability and rate characteristics, highlighting the importance of the control of Gab>2b>Ob>3b>/rGO ratio in optimizing the electrode activity of the composite materials. The present study underscores the usefulness of the phase-control of nanostructured metal oxides achieved by the change of rGO content in exploring novel functional nanocomposite materials.