Coordination-Driven Polymerization of Supramolecular Nanocages
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- 作者：Zheng Niu ; Sheng Fang ; Xiao Liu ; Jian-Gong Ma ; Shengqian Ma ; Peng Cheng
- 刊名：Journal of the American Chemical Society
- 出版年：2015
- 出版时间：December 2, 2015
- 年：2015
- 卷：137
- 期：47
- 页码：14873-14876
- 全文大小：381K
- ISSN：1520-5126
文摘
Controlled assembly of 0D supramolecular nanocages into 2D or 3D architectures has been demonstrated for the first time via a coordination-driven polymerization approach, and the conversion from a 2D to 3D supramolecular architecture has also been successfully achieved via a temperature-induced crystal transformation. The boost of dimensionality for the supramolecular architecture has led to steady yet remarkable enhancement of properties, as reflected from the gas adsorption studies.