Size-Selective Vapochromic Platinum(II) Complex with a Sterically Demanding Pincer-Type N-Heterocyclic Carbene Ligand

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• 作者：Chen-Shiang Lee ; Rui Rui Zhuang ; Shahulhameed Sabiah ; Ju-Chun Wang ; Wen-Shu Hwang ; Ivan J. B. Lin
• 刊名：Organometallics
• 出版年：2011
• 出版时间：July 25, 2011
• 年：2011
• 卷：30
• 期：14
• 页码：3897-3900
• 全文大小：806K
• 年卷期：v.30,no.14(July 25, 2011)
• ISSN：1520-6041

文摘

A pyridine-based pincer-type N-heterocyclic carbene complex of Pt(II), [Pt(II)(^mesCNC)CO](PF₆)₂ (^mesCNC = 2,6-bis(1-mestylimidazol-2-ylidenyl)pyridine), displays size-selective vapochromic behavior upon exposure to small molecules with donor atoms. An acetone adduct showing a weak interaction between acetone and a C鈮 ligand is also structurally determined.