9,10,19,20-Tetraarylporphycenes

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• 作者：K. S. Anju ; S. Ramakrishnan ; Ajesh P. Thomas ; Eringathodi Suresh ; Alagar Srinivasan
• 刊名：Organic Letters
• 出版年：2008
• 出版时间：December 18, 2008
• 年：2008
• 卷：10
• 期：24
• 页码：5545-5548
• 全文大小：182K
• 年卷期：v.10,no.24(December 18, 2008)
• ISSN：1523-7052

文摘

meso-Tetraarylporphycenes, structural isomers of meso-tetraarylporphyrins, were synthesized by the acid-catalyzed oxidative coupling reaction for the first time which is an alternative synthetic methodology to the traditional McMurry coupling reaction. The structure of the macrocycle and Ni(II) complex are characterized by single-crystal X-ray diffraction analyses where both form 1-D supramolecular assembly.