Synthesis and Characterization of the Ferrio-Substituted Silicon(II) Compound Me5C5(CO)2FeSiC5Me5

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• 作者：Peter Jutzi ; Kinga Leszczyska ; Andreas Mix ; Beate Neumann ; Britta Rummel ; Wolfgang Schoeller ; Hans-Georg Stammler
• 刊名：Organometallics
• 出版年：2010
• 出版时间：November 8, 2010
• 年：2010
• 卷：29
• 期：21
• 页码：4759-4761
• 全文大小：728K
• 年卷期：v.29,no.21(November 8, 2010)
• ISSN：1520-6041

文摘

Reaction of the (pentamethylcyclopentadienyl)silicon cation with the (pentamethylcyclopentadienyl)dicarbonylferrate anion leads to the formation of the crystalline, thermolabile silicon(II) compound [(η⁵-pentamethylcyclopentadienyl)dicarbonylferrio](η³-pentamethylcyclopentadienyl)silicon. The singlet−triplet energy difference ΔE_ST is calculated to be 25.4 kcal/mol.