Metal-Free Aromatic Hydrogenation: Aniline to Cyclohexyl-amine Derivatives

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• 作者：Tayseer Mahdi ; Zachariah M. Heiden ; Stefan Grimme ; Douglas W. Stephan
• 刊名：The Journal of the American Chemical Society
• 出版年：2012
• 出版时间：March 7, 2012
• 年：2012
• 卷：134
• 期：9
• 页码：4088-4091
• 全文大小：255K
• 年卷期：v.134,no.9(March 7, 2012)
• ISSN：1520-5126

文摘

Hydrogenation of the N-bound phenyl rings of amines, imines, and aziridine is achieved in the presence of H₂ and B(C₆F₅)₃, affording the corresponding N-cyclohexylammonium hydridoborate salts.