Local Structural Investigations, Defect Formation, and Ionic Conductivity of the Lithium Ionic Conductor Li4P2S6

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• 作者：Christian Dietrich ; Marcel Sadowski ; Sabrina Sicolo ; Dominik A. Weber ; Stefan J. Sedlmaier ; Kai S. Weldert ; Sylvio Indris ; Karsten Albe ; Jürgen Janek ; Wolfgang G. Zeier
• 刊名：Chemistry of Materials
• 出版年：2016
• 出版时间：December 13, 2016
• 年：2016
• 卷：28
• 期：23
• 页码：8764-8773
• 全文大小：667K
• ISSN：1520-5002

文摘

Glassy, glass–ceramic, and crystalline lithium thiophosphates have attracted interest in their use as solid electrolytes in all-solid-state batteries. Despite similar structural motifs, including PS₄^3–, P₂S₆^4–, and P₂S₇^4– polyhedra, these materials exhibit a wide range of possible compositions, crystal structures, and ionic conductivities. Here, we present a combined approach of Bragg diffraction, pair distribution function analysis, Raman spectroscopy, and ³¹P magic angle spinning nuclear magnetic resonance spectroscopy to study the underlying crystal structure of Li₄P₂S₆. In this work, we show that the material crystallizes in a planar structural arrangement as a glass ceramic composite, explaining the observed relatively low ionic conductivity, depending on the fraction of glass content. Calculations based on density functional theory provide an understanding of occurring diffusion pathways and ionic conductivity of this Li⁺ ionic conductor.