Selective Metal Substitution for the Preparation of Heterobimetallic Microporous Coordination Polymers

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• 作者：Stephen R. Caskey ; Adam J. Matzger
• 刊名：Inorganic Chemistry
• 出版年：2008
• 出版时间：September 15, 2008
• 年：2008
• 卷：47
• 期：18
• 页码：7942-7944
• 全文大小：195K
• 年卷期：v.47,no.18(September 15, 2008)
• ISSN：1520-510X

文摘

The designed synthesis of heterobimetallic microporous coordination polymers (MCPs) is reported by a strategy employing the selective replacement of a single metal in homometallic MCPs with two unique metal coordination environments: octahedral and tetrahedral. This strategy is successful in the preparation of six mixed-metal MCPs, where Co/Zn and Ni/Zn versions of MOF-4, MOF-39, and a Zn-BTEC MCP are reported.