Characterization of the Hydrides in Stryker鈥檚 Reagent: [HCu{P(C6H5)3}]6

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• 作者：Elliot L. Bennett ; Patrick J. Murphy ; Silvia Imberti ; Stewart F. Parker
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：March 17, 2014
• 年：2014
• 卷：53
• 期：6
• 页码：2963-2967
• 全文大小：327K
• 年卷期：v.53,no.6(March 17, 2014)
• ISSN：1520-510X

文摘

A structural, spectroscopic, and computational investigation of Stryker鈥檚 reagent, [HCu{P(C₆H₅)₃}]₆, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared and inelastic neutron scattering spectroscopies has allowed the location of most of the modes associated with the hydrides and their assignments. The structural and spectroscopic conclusions are supported by the ab initio studies of the complex.