We report a method to introduce direct bonding between graphene platelets that enables the transformation of a multilayer chemically modified graphene (CMG) film from a 鈥減aper mache-like鈥?structure into a stiff, high strength material. On the basis of chemical/defect manipulation and recrystallization, this technique allows wide-range engineering of mechanical properties (stiffness, strength, density, and built-in stress) in ultrathin CMG films. A dramatic increase in the Young鈥檚 modulus (up to 800 GPa) and enhanced strength (sustainable stress 鈮? GPa) due to cross-linking, in combination with high tensile stress, produced high-performance (quality factor of 31鈥?00 at room temperature) radio frequency nanomechanical resonators. The ability to fine-tune intraplatelet mechanical properties through chemical modification and to locally activate direct carbon鈥揷arbon bonding within carbon-based nanomaterials will transform these systems into true 鈥渕aterials-by-design鈥?for nanomechanics.
Keywords:
Graphene;
cross-linking;
quality factor;
nanomechanics;
resonator;
functionalization