Dinuclear Ruthenium(III)–Ruthenium(IV) Complexes, Having a Doubly Oxido-Bridged and Acetato- or Nitrato-Capped Framework
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- 作者：Tomoyo Suzuki ; Yutaka Suzuki ; Tatsuya Kawamoto ; Ryo Miyamoto ; Shinkoh Nanbu ; Hirotaka Nagao
- 刊名：Inorganic Chemistry
- 出版年：2016
- 出版时间：July 18, 2016
- 年：2016
- 卷：55
- 期：14
- 页码：6830-6832
- 全文大小：239K
- 年卷期：0
- ISSN：1520-510X
文摘
Dinuclear ruthenium complexes in a mixed-valence state of RuIII–RuIV, having a doubly oxido-bridged and acetato- or nitrato-capped framework, [{RuIII,IV(ebpma)}2(μ-O)2(μ-L)](PF6)2 [ebpma = ethylbis(2-pyridylmethyl)amine; L = CH3COO– (1), NO3– (2)], were synthesized. In aqueous solutions, the diruthenium complex 1 showed multiple redox processes accompanied by proton transfers depending on the pH. The protonated complex of 1, which is described as 1H+, was obtained.