Low-Temperature Preparation of Tailored Carbon Nanostructures in Water
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文摘
The development of low-temperature carbonization procedures promises to provide novel nanostructured carbon materials that are of high current interest in materials science and technology. Here, we report a 鈥渨et-chemical鈥?carbonization method that utilizes hexayne amphiphiles as metastable carbon precursors. Nearly perfect control of the nanoscopic morphology was achieved by self-assembly of the precursors into colloidal aggregates with tailored diameter in water. Subsequent carbonization furnished carbon nanocapsules with a carbon microstructure resembling graphite-like amorphous carbon materials.

Keywords:

Graphite-like amorphous carbon; hollow carbon spheres; nanocapsules; oligoynes; oligo(ethynylene)s; carbon-rich amphiphiles

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