Simultaneous Two-Photon Absorption to Gerade Excited Singlet States of Diphenylacetylene and Diphenylbutadiyne Using Optical-Probing Photoacoustic Spectroscopy

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• 作者：Tasuku Isozaki ; Hikari Oba ; Tadaaki Ikoma ; Tadashi Suzuki
• 刊名：Journal of Physical Chemistry A
• 出版年：2016
• 出版时间：August 11, 2016
• 年：2016
• 卷：120
• 期：31
• 页码：6137-6145
• 全文大小：532K
• 年卷期：0
• ISSN：1520-5215

文摘

Simultaneous two-photon absorption to one-photon forbidden electronically excited states of diphenylacetylene (DPA) and diphenylbutadiyne (DPB) was investigated by means of highly sensitive optical-probing photoacoustic spectroscopy. The incident laser power dependencies on photoacoustic signal intensity indicate that the signals are dominated by the two-photon absorption regime. Two-photon absorption is responsible for transitions to gerade excited states based on the selection rule. The two-photon absorption bands observed in the heat action spectra were assigned with the aid of quantum chemical calculations. The relative magnitude of the two-photon absorption cross sections of DPA and DPB was estimated, and the larger two-photon absorption cross section of DPB was related to the resonance effect with the red-shifted one-photon allowed 1¹B_1u ← 1¹A_g transition of DPB.