Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1-Oxides

详细信息    查看全文

• 作者：Taekyu Ryu ; Jaeeun Kim ; Youngchul Park ; Sanghyuck Kim ; Phil Ho Lee
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：August 2, 2013
• 年：2013
• 卷：15
• 期：15
• 页码：3986-3989
• 全文大小：289K
• 年卷期：v.15,no.15(August 2, 2013)
• ISSN：1523-7052

文摘

Rhodium-catalyzed tandem oxidative alkenylation and an intramolecular oxy-Michael reaction were developed using arylphosphonic acid monoethyl esters and alkenes under aerobic conditions, which produced benzoxaphosphole 1-oxides in good to excellent yields.