Proton-Coupled Electron Shuttling in a Covalently Linked Ruthenium鈥揅opper Heterodinuclear Complex

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• 作者：Tomoya Ishizuka ; Kengo Tobita ; Yuichi Yano ; Yoshihito Shiota ; Kazunari Yoshizawa ; Shunichi Fukuzumi ; Takahiko Kojima
• 刊名：Journal of the American Chemical Society
• 出版年：2011
• 出版时间：November 23, 2011
• 年：2011
• 卷：133
• 期：46
• 页码：18570-18573
• 全文大小：754K
• 年卷期：v.133,no.46(November 23, 2011)
• ISSN：1520-5126

文摘

A heterodinuclear complex based on a Ru^II鈥揟PA [TPA = tris(2-pyridylmethyl)amine] complex having a peripheral Cu^II(bpy)₂ (bpy = 2,2鈥?bipyridine) group bonded through an amide linkage displayed reversible intramolecular electron transfer between the Ru and Cu complex units that can be controlled by protonation and deprotonation of the bridging amide moiety.