Isolation and Structural Characterization of a Lewis Base-Free Monolithioferrocene

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• 作者：Takahiro Sasamori ; Yuko Suzuki ; Norihiro Tokitoh
• 刊名：Organometallics
• 出版年：2014
• 出版时间：November 24, 2014
• 年：2014
• 卷：33
• 期：22
• 页码：6696-6699
• 全文大小：250K
• ISSN：1520-6041

文摘

A sterically hindered ferrocenyl lithium derivative was successfully isolated as a stable, crystalline compound without any stabilization by Lewis bases. On the grounds of X-ray crystallography and multinuclear NMR spectroscopy, a dimeric structure was assigned to this monolithioferrocene in the crystalline state and in solution.