The First Isolation and Structural Characterization of a Lanthanoid-Imine Azametallacyclopropane Complex, [Yb(2-Ph2
详细信息 查看全文
- 作者：Yoshikazu Makioka ; Yuki Taniguchi ; Yuzo Fujiwara ; Ken Takaki ; Zhaomin Hou ; and Yasuo Wakatsuki
- 刊名：Organometallics
- 出版年：1996
- 出版时间：December 24, 1996
- 年：1996
- 卷：15
- 期：26
- 页码：5476 - 5478
- 全文大小：75K
- 年卷期：v.15,no.26(December 24, 1996)
- ISSN：1520-6041
文摘
A dianionic lanthanoid(II)-imine azametallacyclopropane complex,[Yb(
2-Ph2CNPh)(hmpa)3](hmpa= hexamethylphosphoramide), has been directly synthesized by the reaction of ytterbium metal withN-(diphenylmethylidene)aniline in THF/HMPA and structurallycharacterized by X-ray analysis.
2-Ph2CNPh)(hmpa)3](hmpa= hexamethylphosphoramide), has been directly synthesized by the reaction of ytterbium metal withN-(diphenylmethylidene)aniline in THF/HMPA and structurallycharacterized by X-ray analysis.