Iridium and Platinum Complexes of Li+@C60

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• 作者：Takahito Watanabe ; Masato F. Itoh ; Takashi Komuro ; Hiroshi Okada ; Takeshi Sakai ; Yoshihiro Ono ; Kazuhiko Kawachi ; Yasuhiko Kasama ; Hiromi Tobita
• 刊名：Organometallics
• 出版年：2014
• 出版时间：February 10, 2014
• 年：2014
• 卷：33
• 期：3
• 页码：608-611
• 全文大小：261K
• ISSN：1520-6041

文摘

Iridium and platinum complexes of the lithium cation encapsulated fullerene Li⁺@C₆₀ were synthesized and structurally determined. The encapsulated Li⁺ strengthens the 蟺 back-bonding from the transition-metal center to the fullerene cage and is attracted toward the two negatively charged carbon atoms bound to the transition metal in the solid state.