A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me3Si(C=NAr)SiMe2(C=NAr)SiMe3 (Ar = 2,6-xylyl), as a New -Diimine Ligand
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- 作者：Masao Tanabiki ; Yusuke Sunada ; Hideo Nagashima
- 刊名：Organometallics
- 出版年：2007
- 出版时间：November 19, 2007
- 年：2007
- 卷：26
- 期：24
- 页码：6055 - 6058
- 全文大小：57K
- 年卷期：v.26,no.24(November 19, 2007)
- ISSN：1520-6041
文摘
A cobalt complex having bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me3Si(C=NAr)SiMe2(C=NAr)SiMe3(Ar = 2,6-xylyl), as a new -diimine ligand was synthesized,and its structure was compared with those of - and -diiminecobalt complexes. Ethylene polymerization catalyzed by thesecobalt complexes and their in situ generated nickel homologueswas investigated.