文摘
Vanadium dioxide (VO2) is a well-known thermochromic material with large IR modulating ability, promising for energy-saving smart windows. The main drawbacks of VO2 are its high phase transition temperature (τc = 68 °C), low luminous transmission (Tlum), and weak solar modulating ability (ΔTsol). In this paper, the terbium cation (Tb3+) doping was first reported to reduce τc and increase Tlum of VO2 thin films. Compared with pristine VO2, 2 at. % doping level gives both enhanced Tlum and ΔTsol from 45.8% to 54.0% and 7.7% to 8.3%, respectively. The Tlum increases with continuous Tb3+ doping and reaches 79.4% at 6 at. % doping level, representing ~73.4% relative increment compared with pure VO2. This has surpassed the best reported doped VO2 thin films. The enhanced thermochromic properties is meaningful for smart window applications of VO2 materials.