Molecular Supertetrahedron Decorated with Exposed Sulfonate Groups Built from Mixed-Valence Tetranuclear Fe33+Fe2+(μ3-Ο)(μ3-SO
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- 作者：Ioanna Papadaki ; Christos D. Malliakas ; Thomas Bakas ; Pantelis N. Trikalitis
- 刊名：Inorganic Chemistry
- 出版年：2009
- 出版时间：November 2, 2009
- 年：2009
- 卷：48
- 期：21
- 页码：9968-9970
- 全文大小：691K
- 年卷期：v.48,no.21(November 2, 2009)
- ISSN：1520-510X
文摘
We present the synthesis and characterization of a novel metal−organic molecular solid using the ligand 4,8-disulfonaphthalene-2,6-dicarboxylic acid. The solid features a sulfonated, isolated supertetrahedra, [Fe16Ο4(SO4)12(L2)6], built from mixed-valence [Fe33+Fe2+(μ3-Ο)(μ3-SO4)3(−CO2)3] clusters.