1,1鈥?Azobis(tetrazole): A Highly Energetic Nitrogen-Rich Compound with a N10 Chain

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• 作者：Thomas M. Klapo虉tke ; Davin G. Piercey
• 刊名：Inorganic Chemistry
• 出版年：2011
• 出版时间：April 4, 2011
• 年：2011
• 卷：50
• 期：7
• 页码：2732-2734
• 全文大小：658K
• 年卷期：v.50,no.7(April 4, 2011)
• ISSN：1520-510X

文摘

The reaction of 1-aminotetrazole with acidic sodium dichloroisocyanurate allowed isolation of 1,1鈥?azobis(tetrazole). The rare chain of 10 nitrogen atoms in this compound was confirmed by X-ray crystallography, and the physical and explosive properties of the azo compound were characterized. The title compound possesses both exceedingly high explosive performance and sensitivity.