The Binary Silver Nitrogen Anion [Ag(N3)2]−
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- 作者：Thomas M. Klapö ; tke ; Burkhard Krumm ; Matthias Scherr
- 刊名：Journal of the American Chemical Society
- 出版年：2009
- 出版时间：January 14, 2009
- 年：2009
- 卷：131
- 期：1
- 页码：72-74
- 全文大小：175K
- 年卷期：v.131,no.1(January 14, 2009)
- ISSN：1520-5126
文摘
The reaction of silver azide with triphenylsulfonium or tetraphenylphosphonium azide results in the formation of the binary silver−nitrogen compound, the novel diazido-argentate(I) anion [Ag(N3)2]−. The crystal structures of both salts of this anion show different cation dependent azide coordination spheres around silver.