Visible Light-Triggered Capture and Release of CO2 from Stable Metal Organic Frameworks

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• 作者：Richelle Lyndon ; Kristina Konstas ; Aaron W. Thornton ; Aaron J. Seeber ; Bradley P. Ladewig ; Matthew R. Hill
• 刊名：Chemistry of Materials
• 出版年：2015
• 出版时间：December 8, 2015
• 年：2015
• 卷：27
• 期：23
• 页码：7882-7888
• 全文大小：562K
• ISSN：1520-5002

文摘

The ability to expose MOF pores on demand using visible light has been demonstrated and exploited for the capture and release of carbon dioxide. Coating of Mg-MOF-74 or MIL-53(Al) with methyl red dye afforded composite materials that became able to adsorb carbon dioxide after exposure to visible light. The Mg-MOF-74 series can be tailored to an 84% uptake change upon irradiation, which is an attractive low-energy alternative for CO₂ capture, where the reliance on coal-based power for materials generation is reduced. Kinetic and temperature dependent studies highlighted the mechanism behind this new effect in MOFs, which varied according to the structural rigidity of the framework.