Superior Performance of Fully Biobased Poly(lactide) via Stereocomplexation-Induced Phase Separation: Structure versus Property

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• 作者：Piming Ma ; Tianfeng Shen ; Pengwu Xu ; Weifu Dong ; Piet J. Lemstra ; Mingqing Chen
• 刊名：ACS Sustainable Chemistry & Engineering
• 出版年：2015
• 出版时间：July 6, 2015
• 年：2015
• 卷：3
• 期：7
• 页码：1470-1478
• 全文大小：461K
• ISSN：2168-0485

文摘

Superior properties such as high strength, toughness and transparency of fully biobased poly(lactide) (PLA) were achieved simultaneously without any external modifiers. The improvement in properties is well explained by a structural/morphological study. Stereocomplex PLA (SC-PLA) was obtained by melt compounding asymmetric poly(l-lactide)/poly(d-lactide) (PLLA/PDLA) blends at 200 掳C and confirmed by wide-angle X-ray diffraction (WAXD) and differential scanning calorimetry (DSC) analyses. The SC-PLA domains (d = 950鈥?200 nm) lead to a physical cross-link network in the PLLA matrix. Rheology and Molau experiment reveal two different microstructures as a function of SC-PLA content, i.e., the connection of SC-PLA domains varied from chain entanglement to direct molecular bridging when the SC-PLA content increased from 10% to 23%. The SC-PLA crystals and the cross-link network reinforced the PLLA matrix, resulting in increases in melt viscosity, modulus and yield strength. Surprisingly, the elongation at break of the PLLA/PDLA blends was increased concomitantly from 11% to 200% with the SC-PLA content up to 10%. The brittle-to-ductile transition is ascribed to the cross-link network and easy deformation/cavitation of the SC-PLA domains. In addition, the asymmetric PLLA/PDLA blends exhibit an average visible light transmittance as high as 70% and the blends showed excellent heat-resistance after a short annealing at 100 掳C.