Enhanced H2 Uptake in Solvents Confined in Mesoporous Metal鈥揙rganic Framework
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- 作者：Stephanie Clauzier ; Linh Ngoc Ho ; Marc Pera-Titus ; Benoit Coasne ; David Farrusseng
- 刊名：The Journal of the American Chemical Society
- 出版年：2012
- 出版时间：October 24, 2012
- 年：2012
- 卷：134
- 期：42
- 页码：17369-17371
- 全文大小：181K
- 年卷期：v.134,no.42(October 24, 2012)
- ISSN：1520-5126
文摘
Hydrogen uptake at 298 K and 30 bar in hybrid sorbents consisting of n-hexane confined in MIL-101 is found to be 22 times larger than in sole n-hexane. The enhanced solubility in MIL-101, found to be 3 times larger than in mesoporous silica of similar pore size, highlights the key roles played by surface chemistry and accessible surface area.