Synthesis of N-Confused Tetraphenylporphyrin Rhodium Complexes Having Versatile Metal Oxidation States

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• 作者：Alagar Srinivasan ; Motoki Toganoh ; Teppei Niino ; Atsuhiro Osuka ; Hiroyuki Furuta
• 刊名：Inorganic Chemistry
• 出版年：2008
• 出版时间：December 1, 2008
• 年：2008
• 卷：47
• 期：23
• 页码：11305-11313
• 全文大小：379K
• 年卷期：v.47,no.23(December 1, 2008)
• ISSN：1520-510X

文摘

A variety of N-confused tetraphenylporphyrin rhodium complexes were synthesized, and their structures and physical properties were investigated. Depending on the reaction conditions, the rhodium(I), -(III), and -(IV) complexes were produced, which exemplified the versatile coordination mode of N-confused porphyrin ligands.