Phosphole-Containing Hybrid Calixpyrroles: New Multifunctional Macrocyclic Ligands for Platinum(II) Ions
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- 作者：Yoshihiro Matano ; Takashi Nakabuchi ; Tooru Miyajima ; and Hiroshi Imahori
- 刊名：Organometallics
- 出版年：2006
- 出版时间：June 19, 2006
- 年：2006
- 卷：25
- 期：13
- 页码：3105 - 3107
- 全文大小：127K
- 年卷期：v.25,no.13(June 19, 2006)
- ISSN：1520-6041
文摘
Phosphole-containing hybrid calixpyrroles have beenprepared by acid-promoted condensation reactions. 
3-Calix[1]phosphole[1]thiophene[2]pyrrole reacts with PtCl2(COD) toafford an unusual type of macrocyclic Pt(II)-monophosphinecomplex bearing a 
3-cyclooctadienyl ligand, in which thephosphole and pyrrole units bind the Pt-Cl moiety throughcooperative, noncovalent bonding interactions.
3-Calix[1]phosphole[1]thiophene[2]pyrrole reacts with PtCl2(COD) toafford an unusual type of macrocyclic Pt(II)-monophosphinecomplex bearing a 3-cyclooctadienyl ligand, in which thephosphole and pyrrole units bind the Pt-Cl moiety throughcooperative, noncovalent bonding interactions.