Reducing the Cost, Smell, and Toxicity of the Barton Reductive Decarboxylation: Chloroform as the Hydrogen Atom Source

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• 作者：Eun Jung Ko ; G. Paul Savage ; Craig M. Williams ; John Tsanaktsidis
• 刊名：Organic Letters
• 出版年：2011
• 出版时间：April 15, 2011
• 年：2011
• 卷：13
• 期：8
• 页码：1944-1947
• 全文大小：692K
• 年卷期：v.13,no.8(April 15, 2011)
• ISSN：1523-7052

文摘

When used as solvent, chloroform was found to act as a hydrogen atom donor in Barton reductive decarboxylation reactions. Chloroform offers a substantial practical advantage over pre-existing hydrogen atom donors.