文摘
We investigate the optical absorption properties of colloidal CdSe nanoplatelets and compare them to CdSe quantum dots. Starting from inductively coupled plasma鈥揳tomic emission spectroscopy (ICP-AES) measurements on their intrinsic absorption coefficients 渭i, we compare these results with a theoretical approach by a continuum absorption Lorentz local field model. We show that the platelets鈥?intrinsic absorption coefficients 渭i are strongly thickness and aspect ratio dependent, which results in the possibility to tune the absorption properties of this material class by the lateral size and thickness. The continuum intrinsic absorbance of the platelets is considerably larger if compared with quantum dots making them more efficient absorbers with higher light鈥搈atter interaction that is essential for their use in, for example, solar cells. The obtained 渭i values can be used for concentration determination of CdSe nanoplatelets in solution and solid films which is essential for all optical experiments with controlled generated population density upon optical excitation.