Systematic Crystallographic Investigation of Hydrogen-Bonded Networks Involving Monohydrogen Tartrate-Amine Complexes: Potential Materials for Nonlinear Optics
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- 作者：Renuka Kadirvelraj ; Arun M. Umarji ; Ward T. Robinson ; Santanu Bhattacharya ; and Tayur N. Guru Row
- 刊名：Chemistry of Materials
- 出版年：1996
- 出版时间：September 1996
- 年：1996
- 卷：8
- 期：9
- 页码：2313 - 2323
- 全文大小：1256K
- 年卷期：v.8,no.9(September 1996)
- ISSN：1520-5002
文摘
Crystal structures of six binary salts involving aromatic aminesas cations and hydrogentartrates as anions are presented. The materials are2,6-xylidinium-L-monohydrogen tartratemonohydrate, C12H18O6.5N,P22121, a =7.283(2) Å, b = 17.030(2) Å, c =22.196(2) Å, Z = 8;2,6-xylidinium-D-dibenzoyl monohydrogen tartrate,C26H25O8N,P21, a = 7.906(1) Å,b =24.757(1) Å, c = 13.166(1) Å, 
=105.01(1)
, Z = 4;2,3-xylidinium-D-dibenzoyl monohydrogentartrate monohydrate, C26H26O8.5N,P21, a = 7.837(1) Å,b = 24.488(1) Å, c = 13.763(1) Å,= 105.69(1), Z = 4;2-toluidinium-D-dibenzoyl monohydrogen tartrate,C25H23O8N,P212121,a = 13.553(2) Å, b = 15.869(3) Å,c = 22.123(2) Å, Z = 8;3-toluidinium-D-dibenzoylmonohydrogen tartrate (1:1),C25H23O8N, P1,a = 7.916(3) Å, b = 11.467(6) Å,c = 14.203(8)Å, 
= 96.44(4), = 98.20(5), =110.55(5), Z = 2;3-toluidinium-D-dibenzoyl tartratedihydrate (1:2), C32H36O10N,P1, a = 7.828(3) Å, b =8.233(1) Å, c = 24.888(8) Å, =93.98, = 94.58(3), = 89.99(2), Z = 2.An analysis of the hydrogen-bonding schemes in termsofcrystal packing, stoichiometric variations, and substitutionalvariations in these materialsprovides insights to design hydrogen-bonded networks directed towardthe engineering ofcrystalline nonlinear optical materials.
=105.01(1), Z = 4;2,3-xylidinium-D-dibenzoyl monohydrogentartrate monohydrate, C26H26O8.5N,P21, a = 7.837(1) Å,b = 24.488(1) Å, c = 13.763(1) Å,= 105.69(1), Z = 4;2-toluidinium-D-dibenzoyl monohydrogen tartrate,C25H23O8N,P212121,a = 13.553(2) Å, b = 15.869(3) Å,c = 22.123(2) Å, Z = 8;3-toluidinium-D-dibenzoylmonohydrogen tartrate (1:1),C25H23O8N, P1,a = 7.916(3) Å, b = 11.467(6) Å,c = 14.203(8)Å, = 96.44(4), = 98.20(5), =110.55(5), Z = 2;3-toluidinium-D-dibenzoyl tartratedihydrate (1:2), C32H36O10N,P1, a = 7.828(3) Å, b =8.233(1) Å, c = 24.888(8) Å, =93.98, = 94.58(3), = 89.99(2), Z = 2.An analysis of the hydrogen-bonding schemes in termsofcrystal packing, stoichiometric variations, and substitutionalvariations in these materialsprovides insights to design hydrogen-bonded networks directed towardthe engineering ofcrystalline nonlinear optical materials.