[Ni(cyclam)(1,3-dca)2Cu(1,5-dca)
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- 作者：Enrique Colacio ; Ikram Ben Maimoun ; Francesc Lloret ; and José ; Suá ; rez-Varela
- 刊名：Inorganic Chemistry
- 出版年：2005
- 出版时间：May 30, 2005
- 年：2005
- 卷：44
- 期：11
- 页码：3771 - 3773
- 全文大小：67K
- 年卷期：v.44,no.11(May 30, 2005)
- ISSN：1520-510X
文摘
The structure of [Ni(cyclam)(
ntities/mgr.gif">1,3-dca)2Cu(ntities/mgr.gif"> 1,5-dca)2], a genuine3D dicyanamide-bridged bimetallic coordination polymer, is madeup of 2D [Cu(ntities/mgr.gif">-1,5dca)2]n layers connected by [Ni(cyclam)(ntities/mgr.gif">1,3-dca)2] bridging moieties; it exhibits a ferromagnetic exchangeinteraction between copper(II) and nickel(II) ions through the ntities/mgr.gif">1,3-bidentate dicyanamide bridges.
ntities/mgr.gif">1,3-dca)2Cu(ntities/mgr.gif"> 1,5-dca)2], a genuine3D dicyanamide-bridged bimetallic coordination polymer, is madeup of 2D [Cu(ntities/mgr.gif">-1,5dca)2]n layers connected by [Ni(cyclam)(ntities/mgr.gif">1,3-dca)2] bridging moieties; it exhibits a ferromagnetic exchangeinteraction between copper(II) and nickel(II) ions through the ntities/mgr.gif">1,3-bidentate dicyanamide bridges.