A New Ru-Catalyzed Cascade Reaction Forming Polycyclic Cyclohexadienes from 1,6-Diynes and Alkenes

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• 作者：Jesú ; s A. Varela ; Silvia G. Rubí ; n ; Carlos Gonz&aacute ; lez-Rodrí ; guez ; Luis Castedo ; and Carlos Sa&aacute
• 刊名：Journal of the American Chemical Society
• 出版年：2006
• 出版时间：July 26, 2006
• 年：2006
• 卷：128
• 期：29
• 页码：9262 - 9263
• 全文大小：48K
• 年卷期：v.128,no.29(July 26, 2006)
• ISSN：1520-5126

文摘

Functionalized bicyclic 1,3-cyclohexadienes can be easily prepared by a new cascade reaction which involves the Ru-catalyzed addition of acyclic alkenes to 1,6-diynes to give (Z)-hexatrienes, followed by a pure thermal 6e^- electrocyclization.