Copper-Catalyzed Allylation of α,α-Difluoro-Substituted Organozinc Reagents

详细信息    查看全文

• 作者：Artem A. Zemtsov ; Nikolay S. Kondratyev ; Vitalij V. Levin ; Marina I. Struchkova ; Alexander D. Dilman
• 刊名：Journal of Organic Chemistry
• 出版年：2014
• 出版时间：January 17, 2014
• 年：2014
• 卷：79
• 期：2
• 页码：818-822
• 全文大小：301K
• ISSN：1520-6904

文摘

A method for the coupling of organozinc reagents, difluorocarbene, and allylic electrophiles is described. The reaction involves insertion of difluorocarbene into the carbon鈥搝inc bond followed by copper-catalyzed allylic substitution.