A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate

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• 作者：Wanling Shen ; Shenhui Li ; Jun Xu ; Hailu Zhang ; Wei Hu ; Dan Zhou ; Jianan Zhang ; Jihong Yu ; Wujun Xu ; Yao Xu ; Feng Deng
• 刊名：Journal of Physical Chemistry C
• 出版年：2010
• 出版时间：April 22, 2010
• 年：2010
• 卷：114
• 期：15
• 页码：7076-7084
• 全文大小：412K
• 年卷期：v.114,no.15(April 22, 2010)
• ISSN：1932-7455

文摘

A novel phase transformation phenomenon that involves two successive phase transformation events was found for the first time in the synthesis of mesostructured aluminophosphate and studied by XRD, TEM, and multinuclear solid-state NMR techniques. The results showed that a hexagonal phase Hex and two lamellar phases, L1 and L2, were formed after hydrothermal treatment for 1, 3, and 50 h, respectively. The status of the surfactant was found to be arrayed interdigitated in a bilayer with a tilt angle in L1 phase but upright in L2 phase. A mechanism that the exciting of the alkane tail of the surfactant together with the condensation of aluminophosphate cooperatively promoted the phase transformation was proposed for the observed phenomenon. Additionally, a ZON microporous structure was found for the first time existing in the framework of the mesostructured aluminophosphate.