C-H and Si-H Activation on Palladium(II) and Platinum(II) Complexes with a New Methoxyalkyl-Substituted Diimine Ligand

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• 作者：Xinggao Fang ; Brian L. Scott ; John G. Watkin ; and Gregory J. Kubas
• 刊名：Organometallics
• 出版年：2000
• 出版时间：October 16, 2000
• 年：2000
• 卷：19
• 期：21
• 页码：4193 - 4195
• 全文大小：58K
• 年卷期：v.19,no.21(October 16, 2000)
• ISSN：1520-6041

文摘

Electrophilic 1,4-bis(methoxypropyl)-2,3-dimethyl-1,4-diazabutadiene Pd(II) and Pt(II) cations 2a,bwith a BAr_F counteranion have been prepared. Complex2a undergoes intramolecular C-H activation to formtricyclic 5, and complex 2b adds to Et₃SiH to form anoctahedral diimine Pt(IV) silyl hydride complex, 7.