Fabrication of Architectures with Dual Hollow Structures: Arrays of Cu2O Nanotubes Organized by Hollow Nanospheres

详细信息    查看全文

• 作者：Jun Xu ; Yong-Bing Tang ; Weixin Zhang ; Chun-Sing Lee ; Zeheng Yang ; Shuit-Tong Lee
• 刊名：Crystal Growth & Design
• 出版年：2009
• 出版时间：October 7, 2009
• 年：2009
• 卷：9
• 期：10
• 页码：4524-4528
• 全文大小：885K
• 年卷期：v.9,no.10(October 7, 2009)
• ISSN：1528-7505

文摘

Highly ordered array of hierarchical nanotubes constructed from Cu₂O hollow nanospheres with a diameter of 165−185 nm and shell thickness of 20−40 nm has been synthesized by using an array of Cu(OH)₂ nanorods as a sacrificial template. The formation of Cu₂O nanotubes is considered to be the result of the “Kirkendall effect”, while evolution of the Cu₂O hollow nanospheres from solid nanospheres in the walls results from the “Ostwald ripening” process. Furthermore, the Kirkendall effect in nanoscaled synthesis has been directly proven by the successful design and synthesis of arrays of Cu₂O/Cu_2−xSe heterogeneous nanotubes constructed from Cu₂O hollow seminanospheres covered on both the inner and the outer surfaces of Cu_2−xSe sheaths with a thickness about 5−10 nm, in which the diffusion rate of copper ions through the Cu_2−xSe sheaths is shown to be double that of ascorbic acid molecules during the reaction process. This work offers a new strategy to study the diffusion rate relationship between diffusion couple in nanoscaled synthesis and provides a novel approach for controllable synthesis of hierarchical architectures with dual hollow nanostructures.