Nickel-Catalyzed C鈥揚 Cross-Coupling of Arylboronic Acids with P(O)H Compounds

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• 作者：Gaobo Hu ; Weizhu Chen ; Tingting Fu ; Zhimin Peng ; Hongwei Qiao ; Yuxing Gao ; Yufen Zhao
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：October 18, 2013
• 年：2013
• 卷：15
• 期：20
• 页码：5362-5365
• 全文大小：249K
• 年卷期：v.15,no.20(October 18, 2013)
• ISSN：1523-7052

文摘

A novel and efficient Ni-catalyzed coupling of a wide range of arylboronic acids with H-phosphites, H-phosphinate esters, and H-phosphine oxides has been developed, providing a general and powerful tool for the synthesis of various aryl-phosphorus compounds, especially for valuable triarylphosphine oxides, in good to excellent yield. This protocol is the first Ni-catalyzed C鈥揚 bond-forming reaction between arylboronic acids and P(O)H compounds.