K2FeGe3Se8: A New Antiferromagnetic Iron Selenide

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• 作者：Kai Feng ; Wendong Wang ; Ran He ; Lei Kang ; Wenlong Yin ; Zheshuai Lin ; Jiyong Yao ; Youguo Shi ; Yicheng Wu
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：February 18, 2013
• 年：2013
• 卷：52
• 期：4
• 页码：2022-2028
• 全文大小：440K
• 年卷期：v.52,no.4(February 18, 2013)
• ISSN：1520-510X

文摘

A new iron selenide, K₂FeGe₃Se₈, has been obtained by spontaneous crystallization. It adopts a new structure type in the noncentrosymmetric monoclinic space group P2₁. In the structure, FeSe₄ and GeSe₄ tetrahedra are connected alternately via corner-sharing to form one-dimensional (1D) _{鈭?/sub>¹[FeGeSe6]^{6鈥?/sup> chains along the a-direction. These chains are further linked by sharing Ge2Se6 units to generate two-dimensional (2D) 鈭?/sub>2[FeGe3Se8]2鈥?/sup> layers stacked parallel to the ac-plane and separated by K+ cations. Deduced from temperature-dependent susceptibility measurement and specific heat measurement under different magnetic fields, K2FeGe3Se8 exhibits an antiferromagnetic transition at 10 K. Furthermore, the magnetic property shows anisotropy between directions parallel and perpendicular to the plane of 鈭?/sub>2[FeGe3Se8]2鈥?/sup> layer. The diffuse reflectance spectra measurement indicates that the band gap of K2FeGe3Se8 is 1.95(2) eV, consistent with the calculated values of 1.80 and 1.53 eV in the spin-up and spin-down directions, respectively. Based on electronic structure calculation, the spin of the Fe2+ cation is 1.85, which is comparable to the experimental value.}}