Caging Peroxide: Anion-Templated Synthesis and Characterization of a Rare-Earth Cluster

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• 作者：William J. Gee ; Jonathan G. MacLellan ; Craig M. Forsyth ; Boujemaa Moubaraki ; Keith S. Murray ; Philip C. Andrews ; Peter C. Junk
• 刊名：Inorganic Chemistry
• 出版年：2012
• 出版时间：August 20, 2012
• 年：2012
• 卷：51
• 期：16
• 页码：8661-8663
• 全文大小：236K
• 年卷期：v.51,no.16(August 20, 2012)
• ISSN：1520-510X

文摘

Sequestration of peroxide derived from molecular oxygen has resulted in the templated synthesis of a terbium picolinate cluster, isolated as a 2D sodiated network in the solid state. This first example of an air-stable rare-earth peroxide cluster represents key evidence for a peroxide-containing intermediate in rare-earth-cluster-catalyzed oxidation reactions. Luminescent and magnetic properties have also been investigated.