Synthesis of Carbon Nanotube鈥揂natase TiO2 Sub-micrometer-sized Sphere Composite Photocatalyst for Synergistic Degradation of Gaseous Styrene

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• 作者：Taicheng An ; Jiangyao Chen ; Xin Nie ; Guiying Li ; Haimin Zhang ; Xiaolu Liu ; Huijun Zhao
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2012
• 出版时间：November 28, 2012
• 年：2012
• 卷：4
• 期：11
• 页码：5988-5996
• 全文大小：616K
• 年卷期：v.4,no.11(November 28, 2012)
• ISSN：1944-8252

文摘

The carbon nanotube (CNT)鈥搒ub-micrometer-sized anatase TiO₂ sphere composite photocatalysts were synthesized by a facile one-step hydrothermal method using titanium tetrafluoride as titanium source and CNTs as structure regulator. Various technologies including X-ray diffraction, UV鈥搗isible absorption spectra, N₂ adsorption鈥揹esorption, scanning electron microscopy, and transmission electron microscopy were employed to characterize the structure properties of the prepared composite photocatalysts. The results indicated that the composite photocatalysts consisted of CNTs wrapping around the sub-micrometer-sized anatase TiO₂ spheres with controllable crystal facets and that the aggregated particles with average diameter ranged from 200 to 600 nm. The fabricated composite photocatalysts were used to degrade gaseous styrene in this work. As expected, a synergistic effect that remarkably enhancing the photocatalytic degradation efficiency of gaseous styrene by the prepared composite photocatalysts was observed in comparison with that the degradation efficiency using pure anatase TiO₂ and the adsorption of CNTs. Similar results were also confirmed in the decolorization of liquid methyl orange. Further investigation demonstrated that the synergistic effect in the photocatalytic activity was related to the structure of the sub-micrometer-sized anatase TiO₂ spheres and the significant roles of CNTs in the composite photocatalysts. By controlling the content of CNTs, the content of TiO₂ or the temperature during the hydrothermal synthesis process, anatase TiO₂ spheres with controllable crystallite size and dominant crystal facets such as {001}, {101}, or polycrystalline could be obtained, which was beneficial for the increase in the synergistic effect and further enhancement of the photocatalytic efficiencies.

Keywords:

CNT-based composite photocatalyst; TiO₂ spheres; structure regulation; photocatalytic activity; synergistic effect